Spoke to brake guy and he said he's almost certain it will be that those pads have hardened/are too hard but gave me some more booster tests to do, connect to vac on the car and then I should be able to move the rod by hand, if not it's dead, if so it's fine. If it tests fine I'll put it all back together and see what happens when I get the pads fully hot at Winton in a few weeks. Annoying because removing the booster was a shit job and putting it back will be worse. Probably shouldn't have jumped the gun in removing it...