Sid dont get too worried about the pfc knock, it doesnt mean the motor is dead at all, get yavuz to have a play with it or come for a drive to the central coast and ill go for a run with you on the freeway and fix it up for you, 5th gear is very high load on the engine thats why it knocks in that gear only, you wouldbe better off tuning it with NO octane booster at all, so run the tank 2 or 3 times with no booster and change the plugs before you get your touch up tune.
a pfc knock of 50 and above is normally close to real knock, but this depends on the condition of the knock sensors.