I have seen similar design brackets as I am running, using 32gtst calipers (for a 280mm rotors), these had been ground out rather severely on the inside to get the caliper to fit over the rotor.. they were the wrong calipers for those brackets. Meant for 33gtst rotors which have longer legs to suit a 296mm rotor, the 32gtst calipers sat 8mm further in, so trying to run 330mm rotors with a 33gtst caliper on brackets meant for 324mm rotors, it's going to clash.. even more so with 32gtst calipers. If the brackets are designed for the calipers to be used, there shouldn't be any real issues with a 324mm rotor setup.. I wouldn't really be going much larger with stock type calipers (hard to find discs in the correct offset though).
Why you'd need anything bigger if you're not running huge slicks is beyond me.. but then you're talking big $$ race car and should be using big $$ brake setups.
I will have some new brackets cut soon that should hopefully solve the problem of clashing with the lower ball joint on 4WD hubs so I can fit some bigger brakes to my heavy ass daily wagon
EDIT: As far as material choice and design, I am a Structural Designer by trade and am confident in the design and materials, maybe one day they will get signed off. I will say I'm not a fan of aluminium brackets, particularly for road use and in the L shaped design I have gone with it would be a really bad idea. The more traditional "dogbone" shaped brackets only really work with larger offsets so you retain adequate edge distance around the holes and even then I wouldn't be going too large.